BTC-500 | Large-scale, battery testing, adiabatic calorimeter
- Characterizing differences in cell performance
- Defining safe operating limits
- Exploring thermal runaways and thermal propagation
Product Category: Battery Testing, Calorimeter
Industry: Batteries
Supplier: H.E.L. Group
Description
Applications
Safety Testing
Define safe operating limits:
- It is essential to identify the safe operating limits of battery cells, modules, and packs in order to avert the risk of thermal runaway, and the potentially catastrophic consequences to which it could lead. Therefore, batteries need to be subjected to mechanical, electrical, and thermal stresses in order to define their safe operating limits.
- Thermal stability data from thermal stress tests can help define the safe working temperature of the battery
- The evaluation of over-charging and discharging rates allows the maximum safe voltage and maximum safe current to be determined
- The consequences of mechanical stresses and external short circuits (ESC) can be evaluated
Exploring thermal runaways and thermal propagation
- In general, most extreme conditions can result in thermal stress on the battery cell, which can lead to a thermal runaway. Therefore, for the development of safe batteries, it is essential to understand the mechanism of the thermal runaway in a cell, and how it propagates within a module or pack so that appropriate mitigation strategies can be implemented.
The data obtained from the stress tests performed in the BTC-130 and the BTC-500 can be used to model a cell’s predicted thermal behavior. Successive onset temperatures of decomposition of components within the cell can be detected, and the resultant heat released determined. This can help to facilitate a mechanistic understanding of the thermal runaway within the cell. Further insight can also be derived from the external analysis of the composition of any evolved gases collected.
The BTC-500 also enables the triggering of a cell at a specific position within a module to undergo a thermal runaway with a mechanical- or electrical-induced short circuit, while the integrated camera will visually capture the event unfolding. The induced thermal runaway allows the risk of thermal propagation to be evaluated, the magnitude of the thermal event to be characterized, and appropriate mitigation measures to be implemented within the module design to ensure heat dissipation is greater than heat generation.
Performance Testing
Characterize differences in cell performance
- The BTC-130 and BTC-500 can be used to characterize the cell performance under more extreme operating conditions. The absolute limit of safe, repeated use can be assessed with the automated cycling of the battery cell until the heat generated by its discharge causes the onset of self-heating. Similarly, puncture tests provide an indication of the structural stability of the cell. The resulting thermal event can also be captured on camera on the BTC-500. These tests enable the safety performance of the cells to be compared.
Features and Options
Type of Test
- Thermal stress: the BTC-500 enables a cell to be subjected to thermal stress under adiabatic conditions, allowing for assessment of its thermal stability and the characterization of thermal runaway events.
- Electrical stress: Full integration with charge-discharge units supports testing of overcharging and discharging rates. External short circuits can also be applied. Resultant thermal runaway events can be characterized under “worst-case”, adiabatic conditions.
- Mechanical stress: the BTC-500 can be equipped to perform nail penetration puncture tests, and allows for the characterization of the subsequent thermal runaway.
- High data rate acquisition, up to 10,000 Hz is available for characterizing extremely fast reactions. 100 Hz data acquisition and unique tests are available for compliance with GB/T 36276-2018
- Additional capabilities to aid further mechanistic understanding of thermal propagation and thermal runaway include:
- Automated gas sampling for vent gas analysis.
- Triggering a cell at a specific position within a module to undergo thermal runaway.
- Integrated video camera to record changes to the test sample.
- Thermal mapping (multipoint temperature measurement) of a sample.
Battery/Sample Size
- Cylindrical cells (upwards from 18650), prismatic cells, pouch cells, and small modules.
- Chamber internal size – 500 mm diameter / 500 mm tall.
Temperature Control
- Ambient to 500 °C.
- Optional: sub-ambient temperatures starting from -40 °C
Intelligent Software Control and Analysis
- Control software enables regular data logging, multi-step recipes, parameter control, and feedback loops.
Safety Features
- Automatic, user-configurable event detection and shutdown procedures, to ensure user safety
- Containment vessel designed to retain fragments and fumes should a sample decompose
- N2 purge for when operating under sub-ambient conditions, or for the safe purging of hazardous gases after a thermal runaway
- Automatic hardware and software fail-safes are installed on every system
Application Notes:
On-Demand Webinars:
- Key Benefits of isothermal and adiabatic calorimetry battery testing
- The Use of Isothermal Calorimetry in Battery Performance Testing
Blogs:
Videos
- Heat Wait Search Video Using H.E.L Battery Testing Calorimeters (BTC)
- With The H.E.L BTC 130 the maximum temperature of the environment which results in a battery thermal explosion that can be predicted by placing the sample in the BTC and performing well-established adiabatic tests. This involves stepwise heating, followed by a wait-and-search period that can be used with cells and large battery packs alike to determine the maximum safe operating temperature.
Whitepapers
Publications
The following are a list of some technical publications which highlight the use of the equipment.
Revealing the multilevel thermal safety of lithium batteries
Gaojie Xu, Lang Huang, Chenglong Lu, Xinhong Zhou, Guanglei Cui
01-Oct-2020
https://doi.org/10.1016/j.ensm.2020.06.004(Subscription or purchase maybe required for full access)
Study on the Performance of Parallel Air-Cooled Structure and Optimized Design for Lithium-Ion Battery Module
Shuai Pan, Changwei Ji, Shuofeng Wang & Bing Wang
28-Jul-2020
https://doi.org/10.1007/s10694-020-01020-x(Subscription or purchase maybe required for full access)
In-Operando Impedance Spectroscopy and Ultrasonic Measurements during High-Temperature Abuse Experiments on Lithium-Ion Batteries
Hendrik Zappen, Georg Fuchs and Alexander Gitis and Dirk Uwe Sauer
22-Apr-2020
https://doi.org/10.3390/batteries6020025(Subscription or purchase maybe required for full access)
Study on thermal stability of nickel-rich/silicon-graphite large capacity lithium ion battery
Hang Li, Xiangbang Kong, Chaoyue Liu, Jinbao Zhao
01-Oct-2019
https://doi.org/10.1016/j.applthermaleng.2019.114144(Subscription or purchase maybe required for full access)
Prediction of the heavy charging current effect on nickel-rich/silicon-graphite power batteries based on adiabatic rate calorimetry measurement
Hang Li, Chaoyue Liu, Xiangbang Kong,Jun Cheng, Jinbao Zhao
01-Oct-2019
https://doi.org/10.1016/j.jpowsour.2019.226971(Subscription or purchase maybe required for full access)
Measurements in abusive tests on lithium ion polymer cells
F. Bianchi; B. Tevenè
14-May-2015
https://doi.org/10.1109/I2MTC.2015.7151419(Subscription or purchase maybe required for full access)